Effect of synthetic zeolite on tobermorite synthesis
 
More details
Hide details
1
Łukasiewicz Research Network, Institute of Ceramics and Building Materials, Kraków, Poland
 
2
Faculty of Civil Engineering and Architecture, Kielce University of Technology, Poland
 
 
Publication date: 2023-02-26
 
 
Cement Wapno Beton 27(5) 320-329 (2022)
 
KEYWORDS
ABSTRACT
This paper presents the results of a study of the effect of synthetic zeolite addition on the formation of tobermorite in a burnt lime-quartz mixture. Synthetic zeolite was obtained by thermal activation of halloysite followed by boiling in sodium hydroxide solution. In this study, the formation of tobermorite was investigated at a constant CaO/SiO2 molar ratio of 0.86 under autoclaving conditions corresponding to saturated steam pressure at 180ºC. The synthesis times were 4 and 12 hours. Synthetic zeolite was added at 5%, 15% and 30%. Studies have shown that synthetic zeolite infl uences the formation of hydrated calcium silicates with poor crystallinity. After 4 hours of autoclaving for samples with synthetic zeolite, a small peak of tobermorite can be found on the XRD pattern. In samples where the molar ratio of Al/(Al+Si) > 0.15 was exceeded, hydrogarnets of the hibschite-katoite group appear. The paper shows that hydrogarnets of the hibschite-katoite group appear for samples with 15% and 30% zeolite after 4 hours of hydrothermal treatment. The intensity of the katoite reflection decreases with increasing autoclaving time and disappears for the sample with 15% zeolite after 12 hours of autoclaving. The presence of portlandite was also demonstrated in these samples.
REFERENCES (19)
1.
S. Komarneni, E. Breval, D.M. Roy, R. Roy, Reactions of some calcium silicates with metal cations. Cem. Concr. Res. 18(2), 204–220 (1988). doi: https://doi.org/10.1016/0008-8....
 
2.
E.A. Blakeman, J.A. Gard, C.G. Ramsay, H.F.W. Taylor, Studies on the system sodium oxide-calcium oxide-silica-water. J. Appl. Chem. Biotechn. 24(4-5), 239–245 (1974). doi: https://doi.org/10.1002/jctb.2....
 
3.
E.B. Nelson, G.L. Kalousek, Effect of Na2O on Calcium Silicate Hydrate at Elevated Temperatures. Cem. Concr. Res. 7(6), 687-694, (1977). doi: https://doi.org/10.1016/0008-8....
 
4.
S. Komarneni, Comparison of cation exchange in ganaphylitte and [Na+Al]- substituted tobermorite: crystal-chemical implications. Miner. Magaz. 52, 371-375, (1988). doi: https://doi.org/10.1180/minmag....
 
5.
Y. Xi, L.S. Dent Glasser, Hydrothermal study in the system Na2O-CaO-SiO2-H2O at 300°C. Cem. Concr. Res. 14(5), 741-748, (1984). doi: https://doi.org/10.1016/0008-8....
 
6.
R. Siauciunas, V. Janickis, D. Palubinskaite, R. Ivanauskas, The sorption properties of tobermorite modified with Na+ and Al3+ ions. Ceramics- Silikaty 48(2), 76-82, (2004).
 
7.
G. Matekonis, R. Sianciunas, D.Vaiciukyniene, Hydrothermal synthesis and characterization of Na+ and [Al3+ + Na+]- substituted tobermorite in CaO-SiO2·nH2O-H2O System. Mater. Sci. (Medžiagotyra).16(3), 242-248, (2010).
 
8.
W. Nocuń- Wczelik, Effect of some additions on autoclaved calcium silicates hydrates. Cem. Concr. Res. 27(1), 83-92, (1997). https://doi.org/10.1016/S0008-....
 
9.
W. Nocuń-Wczelik, Effect of Na and Al on the phase composition and morphology of autoclaved calcium silicate hydrates. Cem. Concr. Res. 29(11), 1759-1767, (1999). https://doi.org/10.1016/S0008-....
 
10.
A. El- Korashy Sabry, Chemical studies on the reactions of synthetic 1.13 nm tobermorite with alkali metal hydroxides at room temperature. Monath. Chem. 128, 599-607, 1997. https://doi.org/10.1007/BF0080....
 
11.
W. Nocuń-Wczelik: Struktura i właściwości uwodnionych krzemianów wapniowych. Prace Komisji Nauk Ceramicznych- Polska Akademia Nauk, Oddział w Krakowie Ceramika, Kraków 1999.
 
12.
C.H. Zhou, T. Sun, Q. Gao, A. Alshameri, P. Zhu, H. Wang, Z. Qiu, Y. Ma, Ch. Yan, Synthesis and characterization ordered mesoporous aluminosilicate molecular sieve from natural halloysite. J. Taiwan Inst. Chem. Eng. 45, 1073-1079, (2014).
 
13.
D.S. Klimesh, A. Ray, DTA-TG study of the CaO-SiO2-H2O and CaO-Al2O3-SiO2-H2O systems under hydrothermal conditions. J. Therm. Anal. Calorimetry 56, 27-34, (1999). https://doi.org/10.1023/A:1010....
 
14.
F. Pertlik, Bibliography of Hibschite, a Hydrogarnet of Grossular Type. GeoLines, 15, 113-119, (2003),.
 
15.
D.S. Klimesh, A. Ray, Effects of quartz particle size on hydrogarnet formation during autoclaving at 180°C in the CaO-SiO2-H2O system. Cem. Concr. Res. 28(9), 1309-1316, (1998). https://doi.org/10.1016/S0008-....
 
16.
D.S. Klimesh, A. Ray, Effects of quartz particle size and kaolin on hydrogarnet formation during autoclaving. Cem. Concr. Res. 28(9), 1317-1323, (1998). https://doi.org/10.1016/S0008-....
 
17.
D.S. Klimesh, A. Ray, Hydrogarnet formation during autoclaving at 180°C in unstirred metakaolin-lime-quartz slurries. Cem. Concr. Res. 28(8), 1109-1117, (1998). https://doi.org/10.1016/S0008-....
 
18.
D.S. Klimesh, A. Ray, DTA-TG evaluations of the CaO-Al2O3-SiO2-H2O system treated hydrothermally. Thermochim. Acta 334(1-2), 115-122, (1999). https://doi.org/10.1016/S0040-....
 
19.
C.A. Langton, E.L. White, W.M. Grutzek, D.M. Roy, High temperature cement with geothermal Application. SPE Oilfield and Geothermal Chemistry Symposium, Stanford, USA, 28-30 May 1980.
 
ISSN:1425-8129
Journals System - logo
Scroll to top